Li, Yuanyuan, et al. Construction and Building Materials 172 (2018): 509-518.
This work demonstrated the application of sodium stearate as an organic modifier to improve the compatibility and anti-aging properties of layered double hydroxides (LDHs) in styrene-butadiene-styrene modified asphalt (SBS MA). By addressing the inherent incompatibility between LDHs and asphalt, sodium stearate significantly enhances the functional performance of LDHs as anti-aging additives.
Methodology: LDHs were organically modified using sodium stearate (SS-LDHs) via a wet modification process: 30g LDHs were dispersed in deionized water, combined with 6% (by weight) sodium stearate, and sheared at 500 r/min for 2 hours at 80°C. The modified SS-LDHs were filtered, washed, and dried. Both unmodified LDHs and SS-LDHs were incorporated into SBS MA at 4.0% concentration via high-shear mixing (4000 r/min, 40 min, 170°C). The aging resistance was evaluated through thin film oven tests (thermo-oxidative aging) and UV aging tests, with performance characterized using FTIR, XRD, SEM, UV-Vis spectroscopy, viscosity, and complex modulus measurements.
Key Findings:
· Sodium stearate modification improved the compatibility between LDHs and SBS MA, enhancing dispersion and storage stability.
· Both LDHs and SS-LDHs improved the resistance to thermo-oxidative and UV aging of SBS MA.
· SS-LDHs demonstrated superior anti-aging performance compared to unmodified LDHs.
· The organic modification process enabled more effective inhibition of age-related degradation in asphalt binders.