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Boric Acid

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  • Product Name: Boric Acid
  • CAS: 10043-35-3
  • Catalog: HG-BULK016
  • Applications: Industrial Manufacturing, Agriculture, Pesticides, Medical Applications, Chemical Synthesis, Metallurgy.

Boric acid, also known as boracic acid or orthoboric acid, is a white, crystalline compound with weakly acidic properties. It is commonly used in the production of glass, ceramics, pesticides, fertilizers, and in medical and cosmetic applications. Alfa Chemistry's boric acid is produced to the highest standards of purity, ensuring its effectiveness and safety across diverse uses.

Key Features

Appearance

  • White, crystalline powder or flaky crystals.

Solubility

  • Easily dissolves in water, alcohol, and glycerol, with solubility increasing in the presence of certain acids like hydrochloric acid and citric acid.

Chemical Properties

  • Boric acid undergoes transformations when heated. At 100-105°C, it loses a molecule of water to form metaboric acid, and at higher temperatures, it converts into boric anhydride.

Technical Data

ItemsSpecification
H3BO3 content≥ 99.99%
Water insoluble matters≤ 0.005%
Sulfate (as SO4)≤ 0.003%
B2O3≥ 56%
Chlorides (as Cl)≤ 0.0005%
Fe≤ 0.0004%
Average grain size80-100 mesh

Applications

Alfa Chemistry's boric acid is used in a variety of industries for different applications:

Industrial Manufacturing

  • Glass Production: It enhances mechanical strength, thermal stability, and optical clarity in optical, acid-resistant, and heat-resistant glass.
  • Paints and Pigments: A key component in the creation of pigments and coatings, improving the luster and durability of enamel and ceramic products.
  • Electronics: Used in the production of capacitors, high-purity analytical reagents, and electronic components.

Agriculture

  • Boron Fertilizer: Boric acid is an essential micronutrient for plants, improving crop yield, quality, and resistance to diseases. It is particularly effective in crops like tomatoes, grapes, and almonds.

Pesticides

  • Insecticide: Used to control pests like cockroaches and carpet beetles, acting as an effective insecticidal agent.

Medical Applications

  • Antiseptic and Antifungal: Commonly used in eye drops, wound dressings, and as an antifungal agent in medical treatments.
  • Preservative: Used as a preservative in pharmaceuticals and cosmetics.

Chemical Synthesis

  • Borates and Borate Esters: Used as a precursor in the production of borates, borate esters, and boron-based chemicals for various applications.

Metallurgy

  • Additive in Boron Steel Production: Boric acid is utilized in metallurgy to produce boron steel, which has superior hardness and rollability.

Storage and Packaging

  • Storage Conditions: Stored in a dry, clean environment to maintain its purity and effectiveness. Keep in a well-ventilated, dry warehouse to prevent moisture absorption and contamination.
  • Packaging: Available in 50 kg bags (plastic-lined woven sacks) and 25 kg paper bags.

Alfa Chemistry's boric acid is a critical chemical with diverse applications. By maintaining strict quality control and ensuring proper storage and transportation conditions, Alfa Chemistry guarantees the safe and effective use of boric acid in industries ranging from agriculture to electronics and pharmaceuticals. For more information, please feel free to contact us.

Case Study

Boric Acid as Cross-Linking Agent for Polyvinyl Alcohol (PVA) Films

The effect of boric acid as a cross-linking agent on PVA film crystallization.Miyazaki, Tsukasa, et al. Polymer 51.23 (2010): 5539-5549.

Boric acid (BA) acts as an efficient cross-linking agent for PVA films, inhibiting recrystallization during heating and enhancing thermal stability by forming covalent bonds with PVA molecular chains in amorphous regions.

Experimental Protocol: PVA films (degree of polymerization 2400) were immersed in 0–3 wt% BA aqueous solutions for 3 min, dried at 60℃. Thermal and structural properties were characterized via DSC, simultaneous SAXS/WAXD, and ICP-MS. Melting behaviors were analyzed by heating from 50–250℃ at 10℃/min.

Performance Evaluation: BA increased PVA's glass transition temperature (Tg) from 67℃ to 80℃ (3 wt% BA) by slowing molecular motion. SAXS/WAXD confirmed BA inhibited crystallite growth (lateral size: 5.7 nm vs. 11.3 nm in neat PVA) and recrystallization during heating. Crystallinity index decreased from 33% to 20% (1 wt% BA), avoiding strain-induced crystallization. BA cross-links stabilized PVA's lamellar structure, critical for high-performance polarizers. It is a cost-effective additive for tailoring PVA film properties in optical and industrial applications.

Boric Acid as Flux Agent for Clay-Based Ceramics Sintering

Property characterization of clay-boric acid-prepared ceramic materials.Hernández, Maria Florencia, et al. Journal of Thermal Analysis & Calorimetry 139.3 (2020).

Boric acid (H3BO3) acts as an efficient flux agent in clay-based ceramics, reducing sintering temperature, promoting glass phase formation, and improving densification via thermal decomposition to B2O3.

Experimental Protocol: Kaolinitic clay was dry-milled with 1–5 wt% H3BO3, pressed into disks (100 MPa), and sintered at 1100–1300℃ (5℃/min, 60 min soak). Characterizations included TG-DTA, XRD-Rietveld, SEM, and Archimedes porosity/density measurements.

Performance Evaluation: H3BO3 lowered optimal sintering temperature by 100–150℃, increasing glass phase content to 70% (vs. 40% without H3BO3). 3 wt% addition reduced open porosity from 24% to 15% at 1300℃ and formed boron-mullite solid solutions. XRD confirmed quartz/cristobalite dispersion in the glass matrix. Excess (5 wt%) H3BO3 caused rehydration and porosity increase. It enables energy-efficient ceramic production, ideal for tiles and refractories with enhanced microstructure homogeneity.

Boric Acid as a Green and Efficient Agent in an Improved Graphene Oxide Synthesis

Procedure, mechanism, and characterization of the synthesis of graphene oxide from boric acid.Zhang, Qiang, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects 652 (2022): 129802.

The widely used Hummers method for synthesizing graphene oxide (GO) relies on sodium nitrate (NaNO3), which generates toxic nitrogen dioxide gases and leaves hard-to-remove ion residues. Furthermore, the process often leads to over-oxidation, creating excessive carbonyl and carboxyl groups that degrade the final graphene's electrical properties. This study developed a modified Hummers method by substituting sodium nitrate with boric acid (H3BO3). This simple yet strategic replacement fundamentally improved the synthesis chemistry. Boric acid acts as a moderating agent during the intense oxidation of graphite, helping to control the reaction pathway and the types of oxygenated functional groups introduced.

Key Performance Improvements

  • Environmental & Safety: Completely eliminated the emission of toxic NO2/N2O4 gases and avoided problematic sodium and nitrate ions in wastewater.
  • Efficiency: The reaction time was shortened to just one hour at room temperature, and the product yield increased by approximately 10%.
  • Product Quality: Spectroscopic analysis (XPS) confirmed that boric acid significantly suppressed the formation of detrimental carbonyl groups. Raman spectroscopy showed the resulting GO had fewer structural defects on its basal plane compared to GO made via the traditional route. This higher structural quality is crucial for restoring conductivity during reduction to graphene.

Implication: Using boric acid as a replacement for sodium nitrate presents a superior, green-chemistry approach to graphene oxide synthesis. It enhances process safety, increases efficiency, and most importantly, produces a higher-quality GO precursor with fewer defects and a more favorable functional group composition.

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