Abdellah Ali, Salah F., et al. Cellulose 27.16 (2020): 9525-9543.
This study combined cellulose acetate propionate (CAP) and cellulose acetate butyrate (CAB) with cellulose acetate (CA) to produce reverse osmosis (RO) membranes. The effects of different combinations on hydrophobicity, salt rejection, and permeate flux were investigated.
Methodology: Pristine and blended RO membranes were fabricated using the phase inversion technique. The casting solution consisted of dioxane (27 wt%), acetone (13.5 wt%), acetic acid (5 wt%), and methanol (10.7 wt%) as solvents and non-solvent. CAB, CA, and CAP were used as membrane materials in varying compositions. The solution was cast on glass plates or polyester fabric supports at a controlled thickness, followed by immersion in an ice-water bath, annealing, and storage in deionized water.
Key Findings:
· The contact angle increased from 56° for pure CA membranes to 74° for CAB membranes, indicating enhanced hydrophobicity.
· Pristine CAB membranes demonstrated a salt rejection rate of 96.8% with a permeate flow of 1.07 L/m2·h.
· Blended membranes, such as CA/0.5 wt% CAB supported on nonwoven polyester fabric, achieved a salt rejection of 91.4% with a permeate flow of 6.05 L/m2·h.
· The incorporation of CAB improved mechanical strength and structural integrity while maintaining competitive desalination performance.