Aminoethylaminopropyltrimethoxysilane

Catalog NumberHG1760243

CAS Number1760-24-3

CategorySilane Coupling Agent

Molecular Weight

222.36

Molecular Formula

C8H22N2O3Si

Boiling Point

259 °C

Flash Point

138 °C

Purity

>97%

Density

1.028 g/mL

Application

Used to promote adhesion between resins that react with amino groups and the surfaces of glass, mineral, metal, etc.

Shelf Life

The shelf life, when the container is stored unopened and under proper conditions above 50 ºF, is expected to be a minimum of two (2) years.

Functional Group

Amino

Refractive Index

1.4300 -1.4500 (25 °C)

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Case Study

Aminoethylaminopropyltrimethoxysilane-Coated Silica for On-Demand Pathogen Removal from Water

Majewski, Peter, et al. Applied surface science 258.7 (2012): 2454-2458.

The objective of this study was to test 3-(2-aminoethyl)aminopropyltrimethoxysilane (Diamo) as a functional coating to prepare a silica material for direct removal of various pathogens from water.The removal process required only gentle mechanical mixing of the surface-engineered silica (SES) material with contaminated water, needing no additional thermal or electrical energy input.
Synthesis: ~450 g silica stirred in 1 L pure water containing 120 mL Diamo for 120 min at room temperature in air. The suspension was left to rest overnight to sediment the powder, then decanted, washed twice with 1 L pure water, and dried at 90 °C for 24 h.
Key Results:
· Zeta potential measurements confirmed that the coating provided the silica particles with a substantially increased positive surface charge. X-ray photoelectron spectrometry and thermogravimetric analysis verified the presence of Diamo on the particle surface, with an amine group concentration of approximately 1 mmol per gram of silica.
· Broad-Spectrum Pathogen Removal: Water treatment studies showed that the material efficiently removed a number of bacteria (E. coli, P. aeruginosa, M. immunogenum, V. cholerae), a virus (poliovirus), and a protozoan (C. parvum) from water. For this, a dose of about 10 grams of SES per liter of water was sufficient to treat samples that had been spiked with concentrations ranging from 102 to 104 colony forming units (cfu; or equivalent) per mL.

Aminoethylaminopropyltrimethoxysilane as an Advanced Copper Adhesion Layer for Semiconductor Interconnects

Rébiscoul, Diane, et al. Langmuir 26.11 (2010): 8981-8987.

Application: Ultra-thin interfacial layers on porous SiOCH low-k dielectrics to enable controlled copper nucleation and deposition in advanced semiconductor packaging.
Challenge: In the fabrication of advanced semiconductor devices, the integration of copper interconnects with porous, low-dielectric-constant (low-k) materials presents a significant challenge. Traditional metallic barrier layers can compromise device performance.
Solution: Aminoethylaminopropyltrimethoxysilane (AEAPTMS) was deposited as an ultrathin silane film onto an O2-plasma-modified porous SiOCH (4000 Å thick) ULK substrate using supercritical CO2 (SC CO2) processes (dynamic and static modes) to produce controlled layer morphologies. Copper was then deposited onto the silanized surfaces by two common techniques - physical vapor deposition (PVD) and metal-organic chemical vapor deposition (MOCVD).
Key Results:
Reflectometry data confirmed that the AEAPTMS layer remained intact following copper deposition via MOCVD at 200°C. The copper film grown on the AEAPTMS layer was found to be dense and thin, and had a microstructure of small copper grains, compared to the thicker and lower-density film with large grains deposited on aminopropyltrimethoxysilane (APTMS).
The results indicated that the final copper film morphology is directly influenced by the specific chemical functionality of the silane and its molecular orientation within the deposited layer, with AEAPTMS showing effective copper immobilization.

• Molecular Weight: 222.36
• Molecular Formula: C8H22N2O3Si
• Boiling Point: 259 °C
• Flash Point: 138 °C
• Purity: >97%
• Density: 1.028 g/mL
• Application: Used to promote adhesion between resins that react with amino groups and the surfaces of glass, mineral, metal, etc.
• Shelf Life: The shelf life, when the container is stored unopened and under proper conditions above 50 ºF, is expected to be a minimum of two (2) years.
• Functional Group: Amino
• Refractive Index: 1.4300 -1.4500 (25 °C)